This led me to consolidation of what I use in case of LiPo powered node, and I ended up with new design of battery power circuit. I have taken out the DC to DC part and added low drop out linear regulator. MCP1700 with excellent quiescent current and drop voltage less then 200mV. I would lost the step up capability, but LiPo operate best in ranges of 4.2V to 3.4V as shown on the picture. Perfect match for such use. Taking a calculator in hand and the datasheet it revels, that the difference in terms of efficiency for LiPo battery is negligible. And in fact as the LiPo discharge it is more convenient to use liner regulator instead of switching, making it more energy efficient! Then single look on quiescent current makes the choice inevitable, linear consumes ~2uA while switching consumes ~80uA. That is 3 times more to what my ATmega328P@16MHz consumes while sleeping.While having battery type set, it is much easier to choose charger circuity. Looking for easy solution I found MCP 73832 a single cell Li-Ion/Li-Po charge management controller. It is small footprint linear charger with charge current programmable by single resistor from 15 mA to 500 mA. Again datasheet stated very low standby current, and it seems to be used in many designs as Google reveals.
I ended up with new version of PCB and called simply node version 1.4. It has micro USB connector for power or charging and charge current set to ~450mA. With a rule of thumb of 1C charging current, it allow use of any Li-Ion or Li-Po battery with capacity bigger then 450mAh. It has no load sharing, but sleeping ATmega is not a problem. I have switched to blue solder mask colour and it is alrady tested and available for sale in my online shop.
I have measured power consumption in various stages to see how it behaves. Where there is range present it is difference between 3.5 and 4.2 input voltage.
MCP1700 quiescent current no other components 2.2uA
Just ATmega328P 16MHz@3V3:
ATmega328P sleeping 25.2uA
ATmega328P running 5.8~6.5mA
With added battery measurement - voltage divider:
ATmega328P sleeping 27.6uA
ATmega328P running 5.8~6.5mA
With added MCP7900 temperature sensor:
ATmega328P sleeping 32.6~33uA
ATmega328P running 5.8~6.5mA
With added MCP73831 charger:
ATmega328P sleeping 33.2~33.6uA
ATmega328P running 5.8~6.5mA
This is major improvement to previous design when Li-Po or Li-Ion battery is used, 1/3 power conumption over version 1.3. while sleeping.

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